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Shizuka Dômeki is Kimihiro Watanuki's classmate and considered a rival by Watanuki. He is part of the school's kyūdō club and often participates (and tops) school competitions. Also because of his cool and calm composure he is very popular with the girls. He has a cool, calm and often sarcastic demeanor. He barely speaks unless explaining folklore or asking Watanuki for impossible bento lunches (such as asking for food that is out of season or hard to find). He also has a deadpan sense of humor that is often dark and somewhat fatalistic. Much to the annoyance of Watanuki he seems to pop up everywhere, especially when Watanuki gets a chance to be with Himawari.

He often replies in a one word phrase like "Hn" or "Oh". He is also very observant, and even though he does not show it he seems to be very protective of Watanuki,

He lives in a shrine owned by his late grandfather, a priest in which during his childhood told him a lot of stories about folklore and shinto practices. However, despite his heritage, Dômeki has a nearly null ability of seeing ghosts or spirits, though he can still exorcise them. He does seem to be able to feel spiritual "pressure" and have a vague sense of their presence. Dômeki cannot enter Yuuko's Store.